Mark Behm's Digital Painting Process - Video
Mark Behm has a fantastic step by step of his process over at Mark's Sketchblog.
I love his approach of starting with a silhouette, doing everything in black and white, painting in the light, constantly flipping it to maintain proportions, using clipping masks and then flattening, and making a color comp and then sampling from that. It goes a bit fast, so I had to watch it a few times, but I like how it wasn't 13 minutes as originally intended.
Now I want to go off and paint, but it's Tuesday so first some figure drawing.